Sunday, 18 December 2011

Light-induced SMPs

Light-activated shape-memory polymers (LASMP) use processes of photo-crosslinking and photo-cleaving to change Tg. Photo-crosslinking is accomplished by application one amicableness of light, while a additional amicableness of ablaze reversibly cleaves the photo-crosslinked bonds. The aftereffect accomplished is that the actual may be reversibly switched amid an elastomer and a adamant polymer. Ablaze does not change the temperature, alone the cross-linking body aural the material.12 For example, it has been appear that polymers absolute cinnamic groups can be anchored into agreed shapes by UV ablaze beam (> 260 nm) and again balance their aboriginal appearance back apparent to UV ablaze of a altered amicableness (< 260 nm).12 Examples of photoresponsive switches accommodate cinnamic acerbic and cinnamylidene acerb acid.

No comments:

Post a Comment